Comparative Study of Hydrogen Sulfide ...
Document type :
Article dans une revue scientifique: Article original
DOI :
PMID :
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Title :
Comparative Study of Hydrogen Sulfide Adsorption in the MIL-53(Al, Cr, Fe), MIL-47(V), MIL-100(Cr), and MIL-101(Cr) Metal-Organic Frameworks at Room Temperature
Author(s) :
Hamon, L. [Auteur]
Serre, C. [Auteur]
Devic, T. [Auteur]
Loiseau, Thierry [Auteur]
Millange, F. [Auteur]
Ferey, G. [Auteur]
De Weireld, G. [Auteur]
Serre, C. [Auteur]
Devic, T. [Auteur]
Loiseau, Thierry [Auteur]

Millange, F. [Auteur]
Ferey, G. [Auteur]
De Weireld, G. [Auteur]
Journal title :
J. Am. Chem. Soc.
Abbreviated title :
J. Am. Chem. Soc.
Pages :
8775-+
Publication date :
2009-06-09
ISSN :
0002-7863
HAL domain(s) :
Chimie
English abstract : [en]
Hydrogen sulfide gravimetric isotherm adsorption measurements were carried out on MIL-53(Al, Cr, Fe), MIL-47(V), MIL-100(Cr), and MIL-101(Cr) metal−organic frameworks (MOFs). A two-step adsorption mechanism related to a ...
Show more >Hydrogen sulfide gravimetric isotherm adsorption measurements were carried out on MIL-53(Al, Cr, Fe), MIL-47(V), MIL-100(Cr), and MIL-101(Cr) metal−organic frameworks (MOFs). A two-step adsorption mechanism related to a breathing effect was observed for MIL-53 terephthalate-based MOFs. Methane adsorption measurements highlighted the regenerability of MIL-53(Al, Cr) and MIL-47(V) MOFs after H2S treatment, whereas MIL-100 and MIL-101 CH4 adsorption capacities were significantly decreased.Show less >
Show more >Hydrogen sulfide gravimetric isotherm adsorption measurements were carried out on MIL-53(Al, Cr, Fe), MIL-47(V), MIL-100(Cr), and MIL-101(Cr) metal−organic frameworks (MOFs). A two-step adsorption mechanism related to a breathing effect was observed for MIL-53 terephthalate-based MOFs. Methane adsorption measurements highlighted the regenerability of MIL-53(Al, Cr) and MIL-47(V) MOFs after H2S treatment, whereas MIL-100 and MIL-101 CH4 adsorption capacities were significantly decreased.Show less >
Language :
Anglais
Administrative institution(s) :
Université de Lille
CNRS
Centrale Lille
ENSCL
Univ. Artois
CNRS
Centrale Lille
ENSCL
Univ. Artois
Collections :
Research team(s) :
Matériaux hybrides (MATHYB)
Submission date :
2023-05-30T18:04:02Z