Systematic study of the condensed phase of phosphorus-based flame retarded foams

Gossiaux, Alexandre; Bellayer, Séverine; Ortgies, Stefan; Wagener, Tobias; König, Alexander; Duquesne, Sophie; Gossiaux, Alexandre

Document type :

Article dans une revue scientifique: Article original

DOI :

10.1016/j.polymdegradstab.2022.110208

Permalink :

http://hdl.handle.net/20.500.12210/85195

Title :

Systematic study of the condensed phase of phosphorus-based flame retarded foams

Author(s) :

Gossiaux, Alexandre [Auteur]
Unité Matériaux et Transformations - UMR 8207 [UMET]
Bellayer, Séverine [Auteur]

Unité Matériaux et Transformations (UMET) - UMR 8207
Ortgies, Stefan [Auteur]

Wagener, Tobias [Auteur]

König, Alexander [Auteur]

Duquesne, Sophie [Auteur]

Unité Matériaux et Transformations (UMET) - UMR 8207
Gossiaux, Alexandre [Auteur]

Journal title :

Polymer Degradation and Stability

Abbreviated title :

Polymer Degradation and Stability

Volume number :

206

Pages :

110208

Publisher :

Elsevier BV

Publication date :

2022-12

ISSN :

0141-3910

HAL domain(s) :

Chimie/Matériaux

English abstract : [en]

This study investigates different types of model phosphorous compounds for flame retardancy purposes to find new FR structures to flame retard rigid poly-isocyanurate (PIR) and/or polyurethane (PUR) foams. Triethylphosphate ...
Show more >This study investigates different types of model phosphorous compounds for flame retardancy purposes to find new FR structures to flame retard rigid poly-isocyanurate (PIR) and/or polyurethane (PUR) foams. Triethylphosphate (TEPate) has been taken as a reference since it is already known to enter into the composition of some FR systems for PIR or PUR foams. Commercially available phosphate, phosphonate, phosphite and phosphine oxide were chosen. All the foam systems were characterized using TGA analysis, rheology tests, and mass loss cone tests, and analyzed using solid state NMR and chemical analysis. DEPonate shows the best efficiency for improving the FR properties of PIR and PUR foam. For the other FRs, the effect on the fire behavior is less relevant especially for PUR foams. This behavior was explained by the fact that even if the FRs slightly decrease the pHRR, the THR or the flaming time, smoke production is usually strongly increased. The systematic study of the condensed phase demonstrates that even if a charring effect is induced by the FR, the effect is not strong enough to improve the FR properties of the material. DEPonate have the least developed char but the best FR properties in PIR and PUR foam, demonstrating that the gas phase effect is more predominant than the condense phase effect.Show less >

Language :

Anglais

Peer reviewed article :

Oui

Audience :

Internationale

Popular science :

Non

Administrative institution(s) :

Université de Lille
CNRS
INRAE
ENSCL

Collections :

Unité Matériaux et Transformations (UMET) - UMR 8207

Research team(s) :

Procédés de Recyclage et de Fonctionnalisation (PReF)

Submission date :

2023-06-27T07:26:11Z
2023-06-30T08:04:13Z

Version	Link	Modification date
2	20.500.12210/85195*	2023-06-30T08:00:01Z
1	20.500.12210/85195.1	2023-06-27T07:26:11Z

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Systematic study of the condensed phase ...

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