Systematic study of the condensed phase of phosphorus-based flame retarded foams

Gossiaux, Alexandre; Bellayer, Séverine; Ortgies, Stefan; Wagener, Tobias; König, Alexander; Duquesne, Sophie; Gossiaux, Alexandre

Type de document :

Article dans une revue scientifique: Article original

DOI :

10.1016/j.polymdegradstab.2022.110208

URL permanente :

http://hdl.handle.net/20.500.12210/85195

Titre :

Systematic study of the condensed phase of phosphorus-based flame retarded foams

Auteur(s) :

Gossiaux, Alexandre [Auteur]
Unité Matériaux et Transformations - UMR 8207 [UMET]
Bellayer, Séverine [Auteur]

Unité Matériaux et Transformations (UMET) - UMR 8207
Ortgies, Stefan [Auteur]

Wagener, Tobias [Auteur]

König, Alexander [Auteur]

Duquesne, Sophie [Auteur]

Unité Matériaux et Transformations (UMET) - UMR 8207
Gossiaux, Alexandre [Auteur]

Titre de la revue :

Polymer Degradation and Stability

Nom court de la revue :

Polymer Degradation and Stability

Numéro :

206

Pagination :

110208

Éditeur :

Elsevier BV

Date de publication :

2022-12

ISSN :

0141-3910

Discipline(s) HAL :

Chimie/Matériaux

Résumé en anglais : [en]

This study investigates different types of model phosphorous compounds for flame retardancy purposes to find new FR structures to flame retard rigid poly-isocyanurate (PIR) and/or polyurethane (PUR) foams. Triethylphosphate ...
Lire la suite >This study investigates different types of model phosphorous compounds for flame retardancy purposes to find new FR structures to flame retard rigid poly-isocyanurate (PIR) and/or polyurethane (PUR) foams. Triethylphosphate (TEPate) has been taken as a reference since it is already known to enter into the composition of some FR systems for PIR or PUR foams. Commercially available phosphate, phosphonate, phosphite and phosphine oxide were chosen. All the foam systems were characterized using TGA analysis, rheology tests, and mass loss cone tests, and analyzed using solid state NMR and chemical analysis. DEPonate shows the best efficiency for improving the FR properties of PIR and PUR foam. For the other FRs, the effect on the fire behavior is less relevant especially for PUR foams. This behavior was explained by the fact that even if the FRs slightly decrease the pHRR, the THR or the flaming time, smoke production is usually strongly increased. The systematic study of the condensed phase demonstrates that even if a charring effect is induced by the FR, the effect is not strong enough to improve the FR properties of the material. DEPonate have the least developed char but the best FR properties in PIR and PUR foam, demonstrating that the gas phase effect is more predominant than the condense phase effect.Lire moins >

Langue :

Anglais

Comité de lecture :

Oui

Audience :

Internationale

Vulgarisation :

Non

Établissement(s) :

Université de Lille
CNRS
INRAE
ENSCL

Collections :

Unité Matériaux et Transformations (UMET) - UMR 8207

Équipe(s) de recherche :

Procédés de Recyclage et de Fonctionnalisation (PReF)

Date de dépôt :

2023-06-27T07:26:11Z
2023-06-30T08:04:13Z

Numéro de version	Lien	Date de modification
2	20.500.12210/85195*	2023-06-30T08:00:01Z
1	20.500.12210/85195.1	2023-06-27T07:26:11Z

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Systematic study of the condensed phase ... BibTeX CSV Excel RIS

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Systematic study of the condensed phase ...

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