Ultra-hydrophobic biomimetic transparent ...
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Article dans une revue scientifique: Article original
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Title :
Ultra-hydrophobic biomimetic transparent bilayer thin film deposited by atmospheric pressure plasma
Author(s) :
Saget, Manon [Auteur]
Institut d’Électronique, de Microélectronique et de Nanotechnologie - UMR 8520 [IEMN]
Unité Matériaux et Transformations - UMR 8207 [UMET]
Nuns, Nicolas [Auteur]
Unité de Catalyse et Chimie du Solide (UCCS) - UMR 8181
Supiot, Philippe [Auteur]
Unité Matériaux et Transformations (UMET) - UMR 8207
Foissac, Corinne [Auteur]
Unité Matériaux et Transformations (UMET) - UMR 8207
Bellayer, Séverine [Auteur]
Unité Matériaux et Transformations (UMET) - UMR 8207
Dourgaparsad, Kevin [Auteur]
Unité Matériaux et Transformations (UMET) - UMR 8207
Royoux, Pierre-Alexandre [Auteur]
Laboratoire des Sciences des Procédés et des Matériaux [LSPM]
Delaplace, Guillaume [Auteur]
Unité Matériaux et Transformations (UMET) - UMR 8207
Thomy, Vincent [Auteur]
Institut d'Électronique, de Microélectronique et de Nanotechnologie (IEMN) - UMR 8520
Coffinier, Yannick [Auteur]
Institut d'Électronique, de Microélectronique et de Nanotechnologie (IEMN) - UMR 8520
Jimenez, Maude [Auteur]
Unité Matériaux et Transformations (UMET) - UMR 8207
Institut d’Électronique, de Microélectronique et de Nanotechnologie - UMR 8520 [IEMN]
Unité Matériaux et Transformations - UMR 8207 [UMET]
Nuns, Nicolas [Auteur]
Unité de Catalyse et Chimie du Solide (UCCS) - UMR 8181
Supiot, Philippe [Auteur]
Unité Matériaux et Transformations (UMET) - UMR 8207
Foissac, Corinne [Auteur]
Unité Matériaux et Transformations (UMET) - UMR 8207
Bellayer, Séverine [Auteur]
Unité Matériaux et Transformations (UMET) - UMR 8207
Dourgaparsad, Kevin [Auteur]
Unité Matériaux et Transformations (UMET) - UMR 8207
Royoux, Pierre-Alexandre [Auteur]
Laboratoire des Sciences des Procédés et des Matériaux [LSPM]
Delaplace, Guillaume [Auteur]
Unité Matériaux et Transformations (UMET) - UMR 8207
Thomy, Vincent [Auteur]
Institut d'Électronique, de Microélectronique et de Nanotechnologie (IEMN) - UMR 8520
Coffinier, Yannick [Auteur]
Institut d'Électronique, de Microélectronique et de Nanotechnologie (IEMN) - UMR 8520
Jimenez, Maude [Auteur]
Unité Matériaux et Transformations (UMET) - UMR 8207
Journal title :
Surfaces and Interfaces
Volume number :
42
Pages :
103398
Publisher :
Elsevier BV
Publication date :
2023-09-19
ISSN :
2468-0230
HAL domain(s) :
Chimie
English abstract : [en]
An open-air atmospheric pressure plasma was used to deposit ultrahydrophobic bilayer coatings. The plasma set-up was tuned, allowing the successive injection in the post-discharge of two monomers. To the best of our ...
Show more >An open-air atmospheric pressure plasma was used to deposit ultrahydrophobic bilayer coatings. The plasma set-up was tuned, allowing the successive injection in the post-discharge of two monomers. To the best of our knowledge, no study describes the successive deposition by atmospheric plasma of two precursors, which could work in synergy and allow designing composite coatings of high added value. In this study, two liquid precursors were chosen for the deposition of single and bilayer coatings: (i) hexamethyldisiloxane (HMDSO) and (ii) 1H,1H,2H,2H-perfluorooctyltriethoxysilane (pFOTES). Single layer coatings (HMDSO and pFOTES) as well as bilayer coating (HMDSO/pFOTES) were analysed using multiscale techniques: Scanning Electron Microscopy (SEM), profilometer, Atomic Force Microscopy (AFM), Fourier-Transformed Infrared Spectroscopy (FTIR), Time-of-Flight Secondary Ion Mass Spectrometry (ToF-SIMS) and drop shape analysis. The bilayer system (HMDSO/pFOTES), resulting from the successive deposition of HMDSO and pFOTES precursors, was confirmed by ToF-SIMS characterization while contact angle measurements highlighted the ultrahydrophobic property of the bilayer: water was fully repelled, with a zero contact angle hysteresis. This resulted from the combination of the multiscale roughnesses of the HMDSO-based and pFOTES based layers, combined with the intrinsic hydrophobicity of the pFOTES layer.Show less >
Show more >An open-air atmospheric pressure plasma was used to deposit ultrahydrophobic bilayer coatings. The plasma set-up was tuned, allowing the successive injection in the post-discharge of two monomers. To the best of our knowledge, no study describes the successive deposition by atmospheric plasma of two precursors, which could work in synergy and allow designing composite coatings of high added value. In this study, two liquid precursors were chosen for the deposition of single and bilayer coatings: (i) hexamethyldisiloxane (HMDSO) and (ii) 1H,1H,2H,2H-perfluorooctyltriethoxysilane (pFOTES). Single layer coatings (HMDSO and pFOTES) as well as bilayer coating (HMDSO/pFOTES) were analysed using multiscale techniques: Scanning Electron Microscopy (SEM), profilometer, Atomic Force Microscopy (AFM), Fourier-Transformed Infrared Spectroscopy (FTIR), Time-of-Flight Secondary Ion Mass Spectrometry (ToF-SIMS) and drop shape analysis. The bilayer system (HMDSO/pFOTES), resulting from the successive deposition of HMDSO and pFOTES precursors, was confirmed by ToF-SIMS characterization while contact angle measurements highlighted the ultrahydrophobic property of the bilayer: water was fully repelled, with a zero contact angle hysteresis. This resulted from the combination of the multiscale roughnesses of the HMDSO-based and pFOTES based layers, combined with the intrinsic hydrophobicity of the pFOTES layer.Show less >
Language :
Anglais
Peer reviewed article :
Oui
Audience :
Internationale
Popular science :
Non
Administrative institution(s) :
Université de Lille
CNRS
INRAE
ENSCL
CNRS
INRAE
ENSCL
Collections :
Research team(s) :
Procédés de Recyclage et de Fonctionnalisation (PReF)
Processus aux Interfaces et Hygiène des Matériaux (PIHM)
Processus aux Interfaces et Hygiène des Matériaux (PIHM)
Submission date :
2023-09-25T08:05:15Z
2023-09-28T08:21:54Z
2023-09-28T08:21:54Z
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