Simultaneous surface modification and ...
Document type :
Article dans une revue scientifique: Article original
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Title :
Simultaneous surface modification and mechanical enhancement of micro/nanofiber fabrics achieved by Janus particles
Author(s) :
Yan, X. [Auteur]
Génie des Matériaux Textiles - ULR 2461 [GEMTEX]
Cayla, A. [Auteur]
Génie des Matériaux Textiles - ULR 2461 [GEMTEX]
Devaux, E. [Auteur]
Génie des Matériaux Textiles - ULR 2461 [GEMTEX]
École nationale supérieure des arts et industries textiles [ENSAIT]
Otazaghine, B. [Auteur]
Polymères Composites et Hybrides [PCH - IMT Mines Alès]
Salaun, Fabien [Auteur]
Génie des Matériaux Textiles - ULR 2461 [GEMTEX]
École nationale supérieure des arts et industries textiles [ENSAIT]
Génie des Matériaux Textiles - ULR 2461 [GEMTEX]
Cayla, A. [Auteur]
Génie des Matériaux Textiles - ULR 2461 [GEMTEX]
Devaux, E. [Auteur]
Génie des Matériaux Textiles - ULR 2461 [GEMTEX]
École nationale supérieure des arts et industries textiles [ENSAIT]
Otazaghine, B. [Auteur]
Polymères Composites et Hybrides [PCH - IMT Mines Alès]
Salaun, Fabien [Auteur]
Génie des Matériaux Textiles - ULR 2461 [GEMTEX]
École nationale supérieure des arts et industries textiles [ENSAIT]
Journal title :
Express Polymer Letters
Volume number :
15
Pages :
-
Publication date :
2021-05-24
ISSN :
1788-618X
English keyword(s) :
polymer composites
micro
nanofiber
polypropylene (PP)
melt-spinning
Janus particles
micro
nanofiber
polypropylene (PP)
melt-spinning
Janus particles
HAL domain(s) :
Sciences de l'ingénieur [physics]
English abstract : [en]
The immiscible polymeric blend of polypropylene (PP) and polyvinyl alcohol (PVA) was manufactured into multifilament fibers via the melt-spinning process, of which the mass ratio of PP to PVA was selected as 30%/70%. The ...
Show more >The immiscible polymeric blend of polypropylene (PP) and polyvinyl alcohol (PVA) was manufactured into multifilament fibers via the melt-spinning process, of which the mass ratio of PP to PVA was selected as 30%/70%. The PP micro/nanofibers were accessible with the removal of PVA in hot water. Kaolinite particles were also incorporated to modify the micro/nanofibers surface, for functionalization efficiencies play a useful role with the aid of a high specific surface area. The octahedral layers of kaolinite particles were grafted with a regioselective process by octadecyl (C18H37-) groups modified into Janus particles to better localize the fillers at the biphasic interface. As a result, the kaolinite particles having a Janus morphology are more distributed at the interface of the polymers, as observed by SEM. The knitting structures are capable of being maintained after the selective phase extraction leaving numbers of micro/nanofibers. After the incorporation of kaolinite particles, there are still some amounts of particles appearing on the surface of PP micro/nanofibers. Besides, there is a mechanical enhancement of the knitted fabrics, especially when the Janus particles are used, even after the selective phase extraction, which the conventional chemical treatment cannot bring. This study sets an example of fabricating PP micro/nanofiber fabrics surface-modified and mechanically enhanced using Janus kaolinite particles.Show less >
Show more >The immiscible polymeric blend of polypropylene (PP) and polyvinyl alcohol (PVA) was manufactured into multifilament fibers via the melt-spinning process, of which the mass ratio of PP to PVA was selected as 30%/70%. The PP micro/nanofibers were accessible with the removal of PVA in hot water. Kaolinite particles were also incorporated to modify the micro/nanofibers surface, for functionalization efficiencies play a useful role with the aid of a high specific surface area. The octahedral layers of kaolinite particles were grafted with a regioselective process by octadecyl (C18H37-) groups modified into Janus particles to better localize the fillers at the biphasic interface. As a result, the kaolinite particles having a Janus morphology are more distributed at the interface of the polymers, as observed by SEM. The knitting structures are capable of being maintained after the selective phase extraction leaving numbers of micro/nanofibers. After the incorporation of kaolinite particles, there are still some amounts of particles appearing on the surface of PP micro/nanofibers. Besides, there is a mechanical enhancement of the knitted fabrics, especially when the Janus particles are used, even after the selective phase extraction, which the conventional chemical treatment cannot bring. This study sets an example of fabricating PP micro/nanofiber fabrics surface-modified and mechanically enhanced using Janus kaolinite particles.Show less >
Language :
Anglais
Peer reviewed article :
Oui
Audience :
Internationale
Popular science :
Non
Administrative institution(s) :
Université de Lille
ENSAIT
Junia HEI
ENSAIT
Junia HEI
Collections :
Submission date :
2023-10-20T05:16:21Z
2024-03-21T07:50:13Z
2024-03-21T07:50:13Z
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