Structure and Mechanical Behavior of Fully Substituted Acid Starch Esters

David, Adelina; Stoclet, Gregory; Joly, Nicolas; Ribeiro, Cedric; Descamps, Nicolas; Lourdin, Denis; Gaucher, Valerie

Document type :

Article dans une revue scientifique: Article original

DOI :

10.1002/macp.202300177

Permalink :

http://hdl.handle.net/20.500.12210/92399

Title :

Structure and Mechanical Behavior of Fully Substituted Acid Starch Esters

Author(s) :

David, Adelina [Auteur]
Unité Matériaux et Transformations - UMR 8207 [UMET]
Stoclet, Gregory [Auteur]

Unité Matériaux et Transformations (UMET) - UMR 8207
Joly, Nicolas [Auteur]
Unité Transformations et Agroressources [Université d'Artois] [UTA]
Ribeiro, Cedric [Auteur]
Unité Matériaux et Transformations (UMET) - UMR 8207
Descamps, Nicolas [Auteur]
Roquette Frères
Lourdin, Denis [Auteur]
Unité de recherche sur les Biopolymères, Interactions Assemblages [BIA]
Gaucher, Valerie [Auteur]

Unité Matériaux et Transformations (UMET) - UMR 8207

Journal title :

Macromolecular Chemistry and Physics

Abbreviated title :

Macro Chemistry & Physics

Volume number :

224

Publisher :

Wiley

Publication date :

2023-09-03

HAL domain(s) :

Chimie/Matériaux

English abstract : [en]

This study deals with the evolution of structural, thermal, and mechanical properties of a series of fully substituted fatty acid starch esters (FASEs) according to side chain length (from 2 (C2) up to 16 (C16) Carbons). ...
Show more >This study deals with the evolution of structural, thermal, and mechanical properties of a series of fully substituted fatty acid starch esters (FASEs) according to side chain length (from 2 (C2) up to 16 (C16) Carbons). FASEs with C2 to C12 side chains are fully amorphous with a glass transition temperature depending on chain length while in the case of FASE with C16 side chains, a part of side chains is able to crystallize. Thermomechanical behavior depends strongly on both the alkyl chain length and crystallinity of samples. In particular, for FASE‐C16, the presence of crystals leads to a brittle behavior. During stretching, no macromolecular orientation is evidenced for short‐chain FASEs (<C8), whereas, for long‐chain starch ester from C8 to C16 length, an orientation of starch backbone in the drawing direction is observed.Show less >

Language :

Anglais

Peer reviewed article :

Oui

Audience :

Internationale

Popular science :

Non

Administrative institution(s) :

Université de Lille
CNRS
INRAE
ENSCL

Collections :

Unité Matériaux et Transformations (UMET) - UMR 8207

Research team(s) :

Ingénierie des Systèmes Polymères

Submission date :

2023-12-11T15:00:45Z
2023-12-13T09:08:42Z
2023-12-13T09:11:20Z

Files

Macro Chemistry Physics - 2023 - David - Structure and Mechanical Behavior of Fully Substituted Acid Starch Esters.pdf
Version éditeur
Open access
Access the document

Except where otherwise noted, this item's license is described as Attribution-NonCommercial-NoDerivs 3.0 United States

Version	Link	Modification date
3	20.500.12210/92399*	2023-12-13T09:10:48Z
2	20.500.12210/92399.2	2023-12-13T08:48:32Z
1	20.500.12210/92399.1	2023-12-11T15:00:45Z

Structure and Mechanical Behavior of Fully ...

BibTeX

CSV

Excel

RIS

Files

Version history

Structure and Mechanical Behavior of Fully ... BibTeX CSV Excel RIS

Files

Version history

Structure and Mechanical Behavior of Fully ...

BibTeX

CSV

Excel

RIS