Copper iodide nanoparticles supported on ...
Document type :
Compte-rendu et recension critique d'ouvrage
Title :
Copper iodide nanoparticles supported on modified graphene-based nanocomposite catalyzed CO2 conversion into oxazolidinone derivatives
Author(s) :
Mirza-Aghayan, Maryam [Auteur]
Alizadeh, Mahdi [Auteur]
Eindhoven University of Technology [Eindhoven] [TU/e]
Boukherroub, Rabah [Auteur]
Institut d’Électronique, de Microélectronique et de Nanotechnologie - UMR 8520 [IEMN]
NanoBioInterfaces - IEMN [NBI - IEMN]
Alizadeh, Mahdi [Auteur]
Eindhoven University of Technology [Eindhoven] [TU/e]
Boukherroub, Rabah [Auteur]
Institut d’Électronique, de Microélectronique et de Nanotechnologie - UMR 8520 [IEMN]
NanoBioInterfaces - IEMN [NBI - IEMN]
Journal title :
Environmental Science and Pollution Research
Pages :
119151-119167
Publisher :
Springer Verlag
Publication date :
2023-11-03
ISSN :
0944-1344
English keyword(s) :
Heterogeneous catalyst
Graphene-based nanocomposite
Copper iodide nanoparticles
CO2 conversion
Oxazolidinone
Vitamin B3
Graphene-based nanocomposite
Copper iodide nanoparticles
CO2 conversion
Oxazolidinone
Vitamin B3
HAL domain(s) :
Physique [physics]
Sciences de l'ingénieur [physics]
Sciences de l'ingénieur [physics]
English abstract : [en]
We report on the preparation of copper iodide nanoparticles (NPs) immobilized on vitamin B3-modified graphene (CuI/GO-VB) nanocomposite and its application for the synthesis of oxazolidinone compounds using a remarkable ...
Show more >We report on the preparation of copper iodide nanoparticles (NPs) immobilized on vitamin B3-modified graphene (CuI/GO-VB) nanocomposite and its application for the synthesis of oxazolidinone compounds using a remarkable carboxylative cyclization method via the reaction of arylacetylene, aldehyde and benzylamine derivatives under an atmospheric pressure of CO2 gas. The CuI/GO-VB catalyst was prepared from graphene oxide (GO), vitamin B3 (VB) and CuI using a two-step procedure; firstly graphene-based composite (GO-VB) was synthesized by the reaction of GO and nicotinoyl chloride, followed by the immobilization of CuI NPs on GO-VB. The CuI/GO-VB nanocomposite was fully identified with X-ray diffraction (XRD), Fourier-transform infrared (FT-IR) spectroscopy, field emission scanning electron microscopy (FESEM), energy dispersive spectroscopy (EDS), inductively coupled plasma optical emission spectroscopy (ICP-OES), transmission electron microscopy (TEM), thermogravimetric analysis (TGA), and X-ray photoelectron spectroscopy (XPS). The catalytic performance of the CuI/GO-VB heterogeneous catalyst was investigated in carboxylative cyclization for the synthesis of oxazolidinone compounds under an atmospheric pressure of CO2 gas at 100οC in solvent-, base-, and additive-free conditions; the corresponding oxazolidinone compounds were obtained in 79–94% yield. The hot filtration results indicated that CuI/GO-VB nanocomposite was a heterogeneous catalyst and showed a good reusability for 5 runs without a significant decrease in its catalytic performance.Show less >
Show more >We report on the preparation of copper iodide nanoparticles (NPs) immobilized on vitamin B3-modified graphene (CuI/GO-VB) nanocomposite and its application for the synthesis of oxazolidinone compounds using a remarkable carboxylative cyclization method via the reaction of arylacetylene, aldehyde and benzylamine derivatives under an atmospheric pressure of CO2 gas. The CuI/GO-VB catalyst was prepared from graphene oxide (GO), vitamin B3 (VB) and CuI using a two-step procedure; firstly graphene-based composite (GO-VB) was synthesized by the reaction of GO and nicotinoyl chloride, followed by the immobilization of CuI NPs on GO-VB. The CuI/GO-VB nanocomposite was fully identified with X-ray diffraction (XRD), Fourier-transform infrared (FT-IR) spectroscopy, field emission scanning electron microscopy (FESEM), energy dispersive spectroscopy (EDS), inductively coupled plasma optical emission spectroscopy (ICP-OES), transmission electron microscopy (TEM), thermogravimetric analysis (TGA), and X-ray photoelectron spectroscopy (XPS). The catalytic performance of the CuI/GO-VB heterogeneous catalyst was investigated in carboxylative cyclization for the synthesis of oxazolidinone compounds under an atmospheric pressure of CO2 gas at 100οC in solvent-, base-, and additive-free conditions; the corresponding oxazolidinone compounds were obtained in 79–94% yield. The hot filtration results indicated that CuI/GO-VB nanocomposite was a heterogeneous catalyst and showed a good reusability for 5 runs without a significant decrease in its catalytic performance.Show less >
Language :
Anglais
Popular science :
Non
Source :