Is it possible to maintain photomechanical ...
Type de document :
Article dans une revue scientifique: Article original
URL permanente :
Titre :
Is it possible to maintain photomechanical properties of crystalline diarylethenes after thermal amorphization?
Auteur(s) :
Louati, Maroua [Auteur]
Unité Matériaux et Transformations (UMET) - UMR 8207
Laboratoire de Spectrochimie et Raman (LASIR) - UMR 8516
Barrau, Sophie [Auteur]
Unité Matériaux et Transformations - UMR 8207 [UMET]
Tahon, Jean-Francois [Auteur]
Unité Matériaux et Transformations (UMET) - UMR 8207
Brosseau, Arnaud [Auteur]
Laboratoire de Photophysique et Photochimie Supramoléculaires et Macromoléculaires [PPSM]
Takao, Marumi [Auteur]
Takeshita, Michinori [Auteur]
Métivier, Rémi [Auteur]
Buntinx, Guy [Auteur]
Laboratoire Avancé de Spectroscopie pour les Intéractions la Réactivité et l'Environnement (LASIRE) - UMR 8516
Aloise, Stephane [Auteur]
Laboratoire Avancé de Spectroscopie pour les Intéractions la Réactivité et l'Environnement (LASIRE) - UMR 8516
Unité Matériaux et Transformations (UMET) - UMR 8207
Laboratoire de Spectrochimie et Raman (LASIR) - UMR 8516
Barrau, Sophie [Auteur]
Unité Matériaux et Transformations - UMR 8207 [UMET]
Tahon, Jean-Francois [Auteur]
Unité Matériaux et Transformations (UMET) - UMR 8207
Brosseau, Arnaud [Auteur]
Laboratoire de Photophysique et Photochimie Supramoléculaires et Macromoléculaires [PPSM]
Takao, Marumi [Auteur]
Takeshita, Michinori [Auteur]
Métivier, Rémi [Auteur]
Buntinx, Guy [Auteur]
![refId](/themes/Mirage2//images/idref.png)
Laboratoire Avancé de Spectroscopie pour les Intéractions la Réactivité et l'Environnement (LASIRE) - UMR 8516
Aloise, Stephane [Auteur]
![refId](/themes/Mirage2//images/idref.png)
Laboratoire Avancé de Spectroscopie pour les Intéractions la Réactivité et l'Environnement (LASIRE) - UMR 8516
Titre de la revue :
Journal of Molecular Structure
Nom court de la revue :
Journal of Molecular Structure
Numéro :
1261
Pagination :
132857
Éditeur :
Elsevier BV
Date de publication :
2022-08
ISSN :
0022-2860
Mot(s)-clé(s) en anglais :
Dithienylethenes
Thermal amorphization
Crystals
Photomechanical properties
Plastic deformations
Material jumping
Thermal amorphization
Crystals
Photomechanical properties
Plastic deformations
Material jumping
Discipline(s) HAL :
Chimie/Matériaux
Chimie/Polymères
Chimie/Polymères
Résumé en anglais : [en]
The photomechanical properties of the photochromic 1,2-bis(2,4-dimethyl-5-phenyl-3-thienyl)perfluorocyclopentene (DTE) crystals, largely documented since the discovery by Irie et al. of its reversible photoswitching of ...
Lire la suite >The photomechanical properties of the photochromic 1,2-bis(2,4-dimethyl-5-phenyl-3-thienyl)perfluorocyclopentene (DTE) crystals, largely documented since the discovery by Irie et al. of its reversible photoswitching of crystallographic plane morphology, is renewed with a novel approach consisting on suppressing gradually dynamical effects through thermal amorphization. In the crystalline case, the reversibility of UV/Visible induced plastic deformations have been observed as expected. In addition, a number of large jumps for both cycles are reported for the first time for this molecule in contrast to being observed only during the first UV irradiation cycle for other DTEs. In the amorphous case, several striking results have been obtained: (i) the still present reversible photoinduced plastic deformations mimicking the crystalline case are interpreted in terms of apparent polyamorphism; (ii) the total vanishing of the jumps brings the evidence of the crucial role of the crystallinity for the propelling surface in contact with the substrate; (iii) the discovery of a never reported material jump during the first visible cycle. This last result is rationalized combining two features –a thermal one, a glass transition temperature very close to the room temperature (Tg ≈ 34°C) and –a photochemical one, an inefficient photoreversion allowing the other vibrational relaxation pathway to proceed inducing the required temperature rise to overpass the phase transition (Solid → Liquid) responsible for the jump.Lire moins >
Lire la suite >The photomechanical properties of the photochromic 1,2-bis(2,4-dimethyl-5-phenyl-3-thienyl)perfluorocyclopentene (DTE) crystals, largely documented since the discovery by Irie et al. of its reversible photoswitching of crystallographic plane morphology, is renewed with a novel approach consisting on suppressing gradually dynamical effects through thermal amorphization. In the crystalline case, the reversibility of UV/Visible induced plastic deformations have been observed as expected. In addition, a number of large jumps for both cycles are reported for the first time for this molecule in contrast to being observed only during the first UV irradiation cycle for other DTEs. In the amorphous case, several striking results have been obtained: (i) the still present reversible photoinduced plastic deformations mimicking the crystalline case are interpreted in terms of apparent polyamorphism; (ii) the total vanishing of the jumps brings the evidence of the crucial role of the crystallinity for the propelling surface in contact with the substrate; (iii) the discovery of a never reported material jump during the first visible cycle. This last result is rationalized combining two features –a thermal one, a glass transition temperature very close to the room temperature (Tg ≈ 34°C) and –a photochemical one, an inefficient photoreversion allowing the other vibrational relaxation pathway to proceed inducing the required temperature rise to overpass the phase transition (Solid → Liquid) responsible for the jump.Lire moins >
Langue :
Anglais
Audience :
Internationale
Vulgarisation :
Non
Établissement(s) :
Université de Lille
CNRS
INRA
ENSCL
CNRS
INRA
ENSCL
Collections :
Équipe(s) de recherche :
Ingénierie des Systèmes Polymères
Date de dépôt :
2022-04-04T05:55:45Z
2022-04-04T06:48:11Z
2022-04-04T06:48:11Z