Title :

The Relationship among Electronic Polarizability, Photoelasticity, and Refractivity in Ternary Phosphate Glasses

Author(s) :

Tomihara, Yusuke [Auteur]
Ehime University [Matsuyama, Japon]
Tricot, Grégory [Auteur]
Laboratoire Avancé de Spectroscopie pour les Intéractions la Réactivité et l'Environnement (LASIRE) - UMR 8516
Revel, Bertrand [Auteur]
Institut Michel Eugène Chevreul - FR 2638 [IMEC]
Kishimoto, Kaoru [Auteur]
Ehime University [Matsuyama, Japon]
Okamoto, Takaya [Auteur]
Ehime University [Matsuyama, Japon]
Saitoh, Akira [Auteur]
Ehime University [Matsuyama, Japon]

Journal title :

physica status solidi (b)

Volume number :

257

Publication date :

2020

HAL domain(s) :

Sciences du Vivant [q-bio]

English abstract : [en]

The optical properties and structural relationships of ternary meta- and pyro-phosphate glasses are found to be correlated with electronic polarizability. In particular, the optical properties of photoelasticity and ...
Show more >The optical properties and structural relationships of ternary meta- and pyro-phosphate glasses are found to be correlated with electronic polarizability. In particular, the optical properties of photoelasticity and refractivity have similar tendencies with electronic polarization evolution, which can be estimated from the Lorentz–Lorenz equation and the compositional data of reported electronic polarizability with small corrections with structural viewpoint. Combinations of the oxide constituents of BaO, SnO, and ZnO result in systematic changes of optical properties, which can be attributed to the phosphate-anion network revealed by 31P magic-angle spinning nuclear magnetic resonance spectroscopy. The small photoelastic constants are obtained with the ubiquitous high polarizable cation of Ba2+ and the substitution of Sn2+ with Zn2+ in the ternary phosphate glasses.Show less >

Audience :

Non spécifiée

Popular science :

Non

Administrative institution(s) :

ENSCL
CNRS
Université de Lille

Collections :

• Laboratoire Avancé de Spectroscopie pour les Intéractions la Réactivité et l'Environnement (LASIRE) - UMR 8516

Research team(s) :

Propriétés magnéto structurales des matériaux (PMSM)

Submission date :

2024-02-21T17:11:52Z
2024-02-23T09:41:52Z