Synthesis of myrcene - isoprene copolymer

Loughmari, Saliha; Visseaux, Marc; Bouazza, Aicha; Hafid, Abderrafia; Bouadili, Abdelaziz El

Document type :

Article dans une revue scientifique: Article original

DOI :

10.24820/ark.5550190.p012.045

Permalink :

http://hdl.handle.net/20.500.12210/112320

Title :

Synthesis of myrcene - isoprene copolymer

Author(s) :

Loughmari, Saliha [Auteur]
Visseaux, Marc [Auteur]

Unité de Catalyse et Chimie du Solide (UCCS) - UMR 8181
Bouazza, Aicha [Auteur]
Hafid, Abderrafia [Auteur]
Bouadili, Abdelaziz El [Auteur]

Journal title :

ARKIVOC - Online Journal of Organic Chemistry

Volume number :

2023

Publisher :

ARKAT USA, Inc.

Publication date :

2023-09-14

ISSN :

1551-7012

HAL domain(s) :

Chimie/Chimie de coordination

English abstract : [en]

The combination of Nd(BH4)3(THF)3 and dialkyl magnesium has enabled a notable achievement in the copolymerization process, with potential for new materials with diverse properties. The copolymerization of myrcene and ...
Show more >The combination of Nd(BH4)3(THF)3 and dialkyl magnesium has enabled a notable achievement in the copolymerization process, with potential for new materials with diverse properties. The copolymerization of myrcene and isoprene has been achieved through statistical copolymerization, with yields of up to 84%. This process allows the insertion of isoprene into poly(1,4-trans-myrcene) while maintaining the regio and stereoselectivity of the reaction, even in the presence of high quantities of isoprene. These findings have important implications for the development of new materials with enhanced properties and demonstrate the potential of this copolymerization method for future applications.Show less >

Language :

Anglais

Audience :

Internationale

Popular science :

Non

Administrative institution(s) :

Université de Lille
CNRS
Centrale Lille
ENSCL
Univ. Artois

Collections :

Unité de Catalyse et Chimie du Solide (UCCS) - UMR 8181

Research team(s) :

Méthodologie organométallique pour la catalyse homogène (MOCAH)

Submission date :

2024-04-02T08:24:07Z

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