Corrosion inhibition properties of ...
Document type :
Article dans une revue scientifique: Article original
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Title :
Corrosion inhibition properties of 4-methyl-2-(methylthio)-3-phenylthiazol-3-ium iodide on the carbon steel in sulfuric acid medium
Author(s) :
Zebida, Mourad [Auteur]
Benali, Omar [Auteur]
Université de Saïda Dr. Moulay Tahar
Maschke, Ulrich [Auteur]
Unité Matériaux et Transformations - UMR 8207 [UMET]
Traisnel, Michel [Auteur]
Unité Matériaux et Transformations - UMR 8207 [UMET]
Benali, Omar [Auteur]
Université de Saïda Dr. Moulay Tahar
Maschke, Ulrich [Auteur]

Unité Matériaux et Transformations - UMR 8207 [UMET]
Traisnel, Michel [Auteur]
Unité Matériaux et Transformations - UMR 8207 [UMET]
Journal title :
International Journal of Corrosion and Scale Inhibition
Abbreviated title :
Int. J. Corros. Scale Inhib.
Volume number :
8
Pages :
613-627
Publisher :
IFHAN
Publication date :
2019-09
ISSN :
2305-6894
HAL domain(s) :
Chimie/Matériaux
Chimie/Polymères
Chimie/Polymères
English abstract : [en]
Weight loss measurement and electrochemical techniques were used as the methods for studying the inhibition effects of 4-methyl-2-(methylthio)-3-phenylthiazol-3-ium iodide (ST1) on carbon steel corrosion in 0.5 M H2SO4. ...
Show more >Weight loss measurement and electrochemical techniques were used as the methods for studying the inhibition effects of 4-methyl-2-(methylthio)-3-phenylthiazol-3-ium iodide (ST1) on carbon steel corrosion in 0.5 M H2SO4. The results reveal that corrosion rate of carbon steel decreases with addition of ST1 in 0.5 M H2SO4. The corrosion rate and inhibition efficiency were found to depend on the concentration of the inhibitor. Inhibition efficiencies up to 99% can be obtained. The polarization data indicated that the inhibitor was of mixed type, with predominant effect on the cathodic partial reaction. Changes in impedance parameters (charge transfer resistance, Rt, and double layer capacitance, Cdl) confirm that corrosion inhibition was due to adsorption on the metal surface following the Langmuir adsorption isotherm. The results obtained from the three different techniques were in good agreement. The influence of the immersion time shows that the inhibiting molecules form a stable and efficient film. XPS analyses clearly show that the adsorption mechanism of ST1 on the carbon steel surface in 0.5 M H2SO4 solution is mainly physical adsorption.Show less >
Show more >Weight loss measurement and electrochemical techniques were used as the methods for studying the inhibition effects of 4-methyl-2-(methylthio)-3-phenylthiazol-3-ium iodide (ST1) on carbon steel corrosion in 0.5 M H2SO4. The results reveal that corrosion rate of carbon steel decreases with addition of ST1 in 0.5 M H2SO4. The corrosion rate and inhibition efficiency were found to depend on the concentration of the inhibitor. Inhibition efficiencies up to 99% can be obtained. The polarization data indicated that the inhibitor was of mixed type, with predominant effect on the cathodic partial reaction. Changes in impedance parameters (charge transfer resistance, Rt, and double layer capacitance, Cdl) confirm that corrosion inhibition was due to adsorption on the metal surface following the Langmuir adsorption isotherm. The results obtained from the three different techniques were in good agreement. The influence of the immersion time shows that the inhibiting molecules form a stable and efficient film. XPS analyses clearly show that the adsorption mechanism of ST1 on the carbon steel surface in 0.5 M H2SO4 solution is mainly physical adsorption.Show less >
Language :
Anglais
Peer reviewed article :
Oui
Audience :
Internationale
Popular science :
Non
Administrative institution(s) :
Université de Lille
CNRS
INRA
ENSCL
CNRS
INRA
ENSCL
Collections :
Research team(s) :
Ingénierie des Systèmes Polymères
Submission date :
2019-11-25T15:16:35Z
2019-11-25T15:57:10Z
2021-01-08T17:57:41Z
2019-11-25T15:57:10Z
2021-01-08T17:57:41Z
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