Title :

Preferential dissolution of copper from Cu-Mn oxides in strong acid medium: Effect of the starting binary oxide to get new efficient copper doped MnO2 catalysts in toluene oxidation

Author(s) :

Ye, Zhiping [Auteur]
Unité de Catalyse et Chimie du Solide - UMR 8181 [UCCS]
Giraudon, Jean-Marc [Auteur]
Unité de Catalyse et Chimie du Solide (UCCS) - UMR 8181
Unité de Catalyse et Chimie du Solide - UMR 8181 [UCCS]
Nuns, Nicolas [Auteur]
Unité de Catalyse et Chimie du Solide (UCCS) - UMR 8181
Unité de Catalyse et Chimie du Solide - UMR 8181 [UCCS]
Abdallah, Grece [Auteur]
Unité de Catalyse et Chimie du Solide - UMR 8181 [UCCS]
Addad, Ahmed [Auteur]
Unité Matériaux et Transformations (UMET) - UMR 8207
Unité Matériaux et Transformations - UMR 8207 [UMET]
Morent, Rino [Auteur]
Department of Applied physics [Ghent]
Universiteit Gent = Ghent University = Université de Gand [UGENT]
De Geyter, Nathalie [Auteur]
Department of Applied physics [Ghent]
Universiteit Gent = Ghent University = Université de Gand [UGENT]
Lamonier, Jean-Francois [Auteur]
Unité de Catalyse et Chimie du Solide (UCCS) - UMR 8181
Unité de Catalyse et Chimie du Solide - UMR 8181 [UCCS]

Journal title :

Applied Surface Science

Abbreviated title :

Applied Surface Science

Volume number :

537

Pages :

147993

Publisher :

Elsevier

Publication date :

2021-01

ISSN :

0169-4332

English keyword(s) :

Preferential dissolution
Acid treatment
ε/γ-MnO2
Toluene
Total oxidation catalysis
Cu-Mn mixed oxides

HAL domain(s) :

Chimie/Catalyse

English abstract : [en]

This work investigated the concept of preferential dissolution of copper in HNO3 10 M at 20 °C from two starting Cu-Mn oxides to acquire novel copper doped MnO2 like polymorphs. On purpose two starting Cu-Mn oxides were ...
Show more >This work investigated the concept of preferential dissolution of copper in HNO3 10 M at 20 °C from two starting Cu-Mn oxides to acquire novel copper doped MnO2 like polymorphs. On purpose two starting Cu-Mn oxides were tested: a nanocristalline CuMn2O4 spinel phase with a SSA of 47 m2/g and a weak amorphous Cu-Mn oxide with a Mn/Cu atomic ratio of 4.8 (SSA: 166 m2/g). The physico-chemical properties of the final copper doped MnO2 like oxides were discussed in terms of the nature of the starting oxides and of the operating conditions applied for the acid treatment. Finally, these new copper doped γ/ε MnO2 like oxides were assessed in toluene oxidation and their catalytic performances were compared with those of α-MnO2 and ε-MnO2 catalysts. The copper doped MnO2 obtained from the weak amorphous Cu-Mn oxide exhibited the highest activity in terms of T50(CO2). This highest activity was related to a high density of Cu-O-Mn interactions at the outermost layers of the catalyst as assessed by ToF-SIMS results.Show less >

Language :

Anglais

Peer reviewed article :

Oui

Audience :

Internationale

Popular science :

Non

Administrative institution(s) :

CNRS
Centrale Lille
ENSCL
INRA
Univ. Artois
Université de Lille

Collections :

• Unité de Catalyse et Chimie du Solide (UCCS) - UMR 8181
• Unité Matériaux et Transformations (UMET) - UMR 8207

Research team(s) :

Remédiation et matériaux catalytiques (REMCAT)

Submission date :

2021-12-08T09:53:20Z
2022-03-01T16:21:18Z
2023-03-23T12:17:09Z
2023-03-24T09:15:35Z
2023-11-13T09:59:32Z
2023-11-14T13:36:59Z