Title :

Mesostructured cmk-3 carbon supported ni-zro2 as catalysts for the hydrodeoxygenation of guaiacol

Author(s) :

Lopez, Monica [Auteur]
Palacio, Ruben [Auteur]
royer, sebastien [Auteur]
Unité de Catalyse et Chimie du Solide - UMR 8181 [UCCS]
Mamede, Anne-Sophie [Auteur]
Unité de Catalyse et Chimie du Solide - UMR 8181 [UCCS]
Fernandez, Jhon Jairo [Auteur]

Journal title :

Microporous and mesoporous materials . the official journal of the International Zeolite Association

Abbreviated title :

Microporous Mesoporous Mat.

Volume number :

292

Publication date :

2019-01-15

ISSN :

1387-1811

Keyword(s) :

HDO
Mesoporous carbon
Zirconium oxide
Nickel
Lignocellulosic biomass
Guaiacol

HAL domain(s) :

Chimie/Catalyse

English abstract : [en]

In this work, mesoporous carbon materials were obtained by using the nanocasting method starting from ordered mesoporous SBA-15 and commercial nonporous Cab-O-sil® M − 5 silica hard templates; materials were named CMK-3 ...
Show more >In this work, mesoporous carbon materials were obtained by using the nanocasting method starting from ordered mesoporous SBA-15 and commercial nonporous Cab-O-sil® M − 5 silica hard templates; materials were named CMK-3 and C-Cab, respectively. These carbon materials, displaying different porous structures (mesopore diameter, specific surface area and pore volume) were used to stabilize Ni and ZrO2 particles using different deposition methods for the nickel and zirconium phases. The catalysts were tested in the hydrodeoxygenation of guaiacol. The conversion varied from 40 to 100% depending on the textural properties of the carbon support and reaction time at 300 °C and under 50 bar of hydrogen pressure. The catalysts were selective toward the formation of the hydrogenation product (methoxycyclohexanol) and hydrogenated - partially deoxygenated product (cyclohexanol). The deposition of the Ni and ZrO2 precursors in mesoporous CMK-3 carbon replicas with a unimodal mesopore diameter, with respect to the use of non-ordered carbons, allows to obtain improved selectivity toward cyclohexanol and, more importantly, toward cyclohexane. Preparation using incipient-wetness impregnation favoured the formation of both monoclinic and tetragonal phases, while the deposition-precipitation method led to the formation of ZrO2 with a unique tetragonal structure. The presence of both monoclinic and tetragonal phases modified the density of catalyst acid sites, which allow to improve the selectivity toward cyclohexane and cyclohexanol while decreasing the selectivity toward the undesired methoxycyclohexanol and other oxygenated compounds.Show less >

Language :

Anglais

Audience :

Internationale

Popular science :

Non

Administrative institution(s) :

CNRS
Centrale Lille
ENSCL
Univ. Artois
Université de Lille

Collections :

• Unité de Catalyse et Chimie du Solide (UCCS) - UMR 8181

Research team(s) :

Matériaux pour la catalyse (MATCAT)

Submission date :

2022-03-02T07:14:12Z
2023-11-28T14:41:53Z