Study of the Direct CO2 Carboxylation Reaction on Supported Metal Nanoparticles

Drault, Fabien; Snoussi, Youssef; Thuriot, Joelle; Itabaiana, Ivaldo; PAUL, Sébastien; Wojcieszak, Robert

Document type :

Article dans une revue scientifique: Article original

DOI :

10.3390/catal11030326

Permalink :

http://hdl.handle.net/20.500.12210/62109

Title :

Study of the Direct CO2 Carboxylation Reaction on Supported Metal Nanoparticles

Author(s) :

Drault, Fabien [Auteur]
Unité de Catalyse et Chimie du Solide (UCCS) - UMR 8181
Snoussi, Youssef [Auteur]
Unité de Catalyse et de Chimie du Solide (UCCS) - UMR 8181
Thuriot, Joelle [Auteur]

Unité de Catalyse et Chimie du Solide (UCCS) - UMR 8181
Itabaiana, Ivaldo [Auteur]
Unité de Catalyse et Chimie du Solide (UCCS) - UMR 8181
PAUL, Sébastien [Auteur]

Unité de Catalyse et Chimie du Solide (UCCS) - UMR 8181
Wojcieszak, Robert [Auteur]

Unité de Catalyse et Chimie du Solide (UCCS) - UMR 8181

Journal title :

Catalysts

Abbreviated title :

Catalysts

Volume number :

Pages :

326

Publication date :

2021-03-04

ISSN :

2073-4344

HAL domain(s) :

Chimie/Catalyse

English abstract : [en]

2,5-furandicarboxylic acid (2,5-FDCA) is a biomass derivate of high importance that is used as a building block in the synthesis of green polymers such as poly(ethylene furandicarboxylate) (PEF). PEF is presumed to be an ...
Show more >2,5-furandicarboxylic acid (2,5-FDCA) is a biomass derivate of high importance that is used as a building block in the synthesis of green polymers such as poly(ethylene furandicarboxylate) (PEF). PEF is presumed to be an ideal substitute for the predominant polymer in industry, the poly(ethylene terephthalate) (PET). Current routes for 2,5-FDCA synthesis require 5-hydroxymethylfurfural (HMF) as a reactant, which generates undesirable co-products due to the complicated oxidation step. Therefore, direct CO2 carboxylation of furoic acid salts (FA, produced from furfural, derivate of inedible lignocellulosic biomass) to 2,5-FDCA is potentially a good alternative. Herein, we present the primary results obtained on the carboxylation reaction of potassium 2-furoate (K2F) to synthesize 2,5-FDCA, using heterogeneous catalysts. An experimental setup was firstly validated, and then several operation conditions were optimized, using heterogeneous catalysts instead of the semi-heterogeneous counterparts (molten salts). Ag/SiO2 catalyst showed interesting results regarding the K2F conversion and space–time yield of 2,5-FDCA.Show less >

Language :

Anglais

Audience :

Internationale

Popular science :

Non

Administrative institution(s) :

CNRS
Centrale Lille
ENSCL
Univ. Artois
Université de Lille

Collections :

Unité de Catalyse et Chimie du Solide (UCCS) - UMR 8181

Research team(s) :

Valorisation des alcanes et de la biomasse (VAALBIO)

Submission date :

2022-03-24T09:03:07Z
2023-02-01T09:23:58Z

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Except where otherwise noted, this item's license is described as Attribution 3.0 United States

Version	Link	Modification date
2	20.500.12210/62109*	2023-02-01T09:22:18Z
1	20.500.12210/62109.1	2022-03-24T09:03:07Z

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