Au@BN-enhanced laser desorption/ionization ...
Type de document :
Compte-rendu et recension critique d'ouvrage
Titre :
Au@BN-enhanced laser desorption/ionization mass spectrometry and imaging for determination of fipronil and its metabolites in food and biological samples
Auteur(s) :
Zhao, Yanfang [Auteur]
China University of Geosciences [Beijing]
Boukherroub, Rabah [Auteur]
NanoBioInterfaces - IEMN [NBI - IEMN]
Institut d’Électronique, de Microélectronique et de Nanotechnologie - UMR 8520 [IEMN]
Xu, Guiju [Auteur]
Li, Huijuan [Auteur]
Universität Bayreuth [Deutschland] = University of Bayreuth [Germany] = Université de Bayreuth [Allemagne]
Zhao, Ru-Song [Auteur]
Wei, Qin [Auteur]
Yu, Xiang [Auteur correspondant]
China University of Geosciences [Beijing]
Chen, Xiangfeng [Auteur correspondant]
China University of Geosciences [Beijing]
Boukherroub, Rabah [Auteur]

NanoBioInterfaces - IEMN [NBI - IEMN]
Institut d’Électronique, de Microélectronique et de Nanotechnologie - UMR 8520 [IEMN]
Xu, Guiju [Auteur]
Li, Huijuan [Auteur]
Universität Bayreuth [Deutschland] = University of Bayreuth [Germany] = Université de Bayreuth [Allemagne]
Zhao, Ru-Song [Auteur]
Wei, Qin [Auteur]
Yu, Xiang [Auteur correspondant]
China University of Geosciences [Beijing]
Chen, Xiangfeng [Auteur correspondant]
Titre de la revue :
Food Chemistry
Pagination :
135935
Éditeur :
Elsevier
Date de publication :
2023-08
ISSN :
0308-8146
Mot(s)-clé(s) en anglais :
Fipronil
Metabolites
Au@BN
LDI-MS
Imaging
Food matrices
Metabolites
Au@BN
LDI-MS
Imaging
Food matrices
Discipline(s) HAL :
Physique [physics]
Sciences de l'ingénieur [physics]
Sciences de l'ingénieur [physics]
Résumé en anglais : [en]
AbstractGold nanoparticles (AuNPs) represent an attractive inorganic matrix for laser desorption/ionization mass spectrometry (LDI-MS) detection of low-molecular-weight analytes; however, their direct use is hindered by ...
Lire la suite >AbstractGold nanoparticles (AuNPs) represent an attractive inorganic matrix for laser desorption/ionization mass spectrometry (LDI-MS) detection of low-molecular-weight analytes; however, their direct use is hindered by severe aggregation. To limit AuNPs aggregation, hexagonal boron nitride nanosheets (h-BNNs) were employed as supports to improve their desorption/ionization efficiency. Thus, Au@BN was synthesized and systematically characterized. It showed low background noise and high sensitivity for LDI-MS of fipronil and its metabolites. Au@BN-assisted LDI-MS was validated using complex samples including blueberry juice, green tea beverage, and fish muscle, achieving low detection limits (0.05–0.20 µg·L−1 for liquid media, 0.82–1.25 ng·g−1 for fish muscle), wide linear ranges (0.2–100 µg·L−1 for liquid media, 3.00–1000 ng·g−1 for fish muscle), high reproducibility (7.55%–13.7%), and satisfactory recoveries (82.62%–109.1%). Furthermore, spatial distributions of analytes in strawberries and zebrafish were successfully imaged. This strategy allows for the quantitative analysis of other small molecules in complex substrates.Lire moins >
Lire la suite >AbstractGold nanoparticles (AuNPs) represent an attractive inorganic matrix for laser desorption/ionization mass spectrometry (LDI-MS) detection of low-molecular-weight analytes; however, their direct use is hindered by severe aggregation. To limit AuNPs aggregation, hexagonal boron nitride nanosheets (h-BNNs) were employed as supports to improve their desorption/ionization efficiency. Thus, Au@BN was synthesized and systematically characterized. It showed low background noise and high sensitivity for LDI-MS of fipronil and its metabolites. Au@BN-assisted LDI-MS was validated using complex samples including blueberry juice, green tea beverage, and fish muscle, achieving low detection limits (0.05–0.20 µg·L−1 for liquid media, 0.82–1.25 ng·g−1 for fish muscle), wide linear ranges (0.2–100 µg·L−1 for liquid media, 3.00–1000 ng·g−1 for fish muscle), high reproducibility (7.55%–13.7%), and satisfactory recoveries (82.62%–109.1%). Furthermore, spatial distributions of analytes in strawberries and zebrafish were successfully imaged. This strategy allows for the quantitative analysis of other small molecules in complex substrates.Lire moins >
Langue :
Anglais
Vulgarisation :
Non
Source :