Titre :

Hydrogen Production through Aqueous-Phase Reforming of Ethylene Glycol in a Washcoated Microchannel

Auteur(s) :

D''angelo, M. F. N. [Auteur]
Ordomsky, Vitaly [Auteur]
Paunovic, V. [Auteur]
Van Der Schaaf, J. [Auteur]
Schouten, J. C. [Auteur]
Nijhuis, T. A. [Auteur]

Titre de la revue :

ChemSusChem

Nom court de la revue :

ChemSusChem

Pagination :

1708-1716

Date de publication :

2013-04-16

ISSN :

1864-5631

Mot(s)-clé(s) en anglais :

XANES
EXAFS
DRX
soil
sorption
copper

Discipline(s) HAL :

Chimie

Résumé en anglais : [en]

Aqueous-phase reforming (APR) of biocarbohydrates is conducted in a catalytically stable washcoated microreactor where multiphase hydrogen removal enhances hydrogen efficiency. Single microchannel experiments are conducted ...
Lire la suite >Aqueous-phase reforming (APR) of biocarbohydrates is conducted in a catalytically stable washcoated microreactor where multiphase hydrogen removal enhances hydrogen efficiency. Single microchannel experiments are conducted following a simplified model based on the microreactor concept. A coating method to deposit a Pt-based catalyst on the microchannel walls is selected and optimized. APR reactivity tests are performed by using ethylene glycol as the model compound. Optimum results are achieved with a static washcoating technique; a highly uniform and well adhered 5 μm layer is deposited on the walls of a 320 μm internal diameter (ID) microchannel in one single step. During APR of ethylene glycol, the catalyst layer exhibits high stability over 10 days after limited initial deactivation. The microchannel presents higher conversion and selectivity to hydrogen than a fixed-bed reactor. The benefits of using a microreactor for APR can be further enhanced by utilizing increased Pt loadings, higher reaction temperatures, and larger carbohydrates (e.g., glucose). The use of microtechnology for aqueous-phase reforming will allow for a great reduction in the reformer size, thus rendering it promising for distributed hydrogen production.Lire moins >

Langue :

Anglais

Établissement(s) :

Université de Lille
CNRS
Centrale Lille
ENSCL
Univ. Artois

Collections :

• Unité de Catalyse et Chimie du Solide (UCCS) - UMR 8181

Équipe(s) de recherche :

Catalyse pour l’énergie et la synthèse de molécules plateforme (CEMOP)

Date de dépôt :

2023-05-30T17:02:24Z