Titre :

Resolution enhancement in 1D solid-state NMR spectra of spin-9/2 quadrupolar nuclei

Auteur(s) :

Amoureux, Jean-Paul [Auteur]
Trebosc, Julien [Auteur]

Titre de la revue :

J. Magn. Reson.

Nom court de la revue :

J. Magn. Reson.

Pagination :

311-316

Date de publication :

2006-06

ISSN :

1090-7807

Mot(s)-clé(s) en anglais :

magic-angle spinning NMR
quadrupolar nuclei
satellite-transition MAS
high-resolution
homogenous broadening

Discipline(s) HAL :

Chimie

Résumé en anglais : [en]

NMR is an insensitive spectroscopy, which often requires numerous accumulations, especially for 2D high-resolution methods (MQMAS and STMAS) for quadrupolar nuclei in solids. This may be a very important limitation for the ...
Lire la suite >NMR is an insensitive spectroscopy, which often requires numerous accumulations, especially for 2D high-resolution methods (MQMAS and STMAS) for quadrupolar nuclei in solids. This may be a very important limitation for the case of insensitive nuclei, where a 1D spectrum with better resolution than the central-transition is then highly desirable. This problem has been addressed for the case of spin-5/2 nuclei by the Double-Quantum Filtered Satellite Transition Spectroscopy: DQF-SATRAS-ST1. We extend this concept to the spin-9/2 nuclei with the SATRAS-ST2 method. This method allows the observation of 1D spectra with a much better resolution than that observed in the isotropic projection of 2D MQ/ST1-MAS spectra. This enhanced resolution results from the much smaller homogeneous broadening that occurs on the SATRAS-ST2 method as compared to MQ/ST1-MAS spectra. The main interest in this method is for well-crystallized samples.Lire moins >

Langue :

Anglais

Établissement(s) :

Université de Lille
CNRS
Centrale Lille
ENSCL
Univ. Artois

Collections :

• Unité de Catalyse et Chimie du Solide (UCCS) - UMR 8181

Équipe(s) de recherche :

RMN et matériaux inorganiques (RM2I)

Date de dépôt :

2023-05-30T18:30:36Z