Titre :

Positional and Rotational Molecular Degrees of Freedom at a Roughened Metal–Organic Interface: The Copper–Fullerene System and Its Multiple Structural Phases

Auteur(s) :

Alfonso Moro, María [Auteur]
Micro et NanoMagnétisme [NEEL - MNM]
Dappe, Y. J. [Auteur]
Service de physique de l'état condensé [SPEC - UMR3680]
Godey, Sylvie [Auteur]
Institut d’Électronique, de Microélectronique et de Nanotechnologie - UMR 8520 [IEMN]
Plateforme de Caractérisation Multi-Physiques - IEMN [PCMP - IEMN]
Melin, Thierry [Auteur]
Physique - IEMN [PHYSIQUE - IEMN]
Institut d’Électronique, de Microélectronique et de Nanotechnologie - UMR 8520 [IEMN]
González, César [Auteur]
Universidad Complutense de Madrid = Complutense University of Madrid [Madrid] [UCM]
Guisset, Valérie [Auteur]
Epitaxie et couches minces [NEEL- EpiCM]
David, Philippe [Auteur]
Epitaxie et couches minces [NEEL- EpiCM]
Canals, Benjamin [Auteur]
Théorie de la Matière Condensée [NEEL - TMC]
Rougemaille, N. [Auteur]
Micro et NanoMagnétisme [NEEL - MNM]
Coraux, Johann [Auteur correspondant]
Interactions modulables dans des états quantiques 2D [NEEL - Quan2m]

Titre de la revue :

Journal of Physical Chemistry C

Pagination :

18765–18777

Éditeur :

American Chemical Society

Date de publication :

2023

ISSN :

1932-7447

Mot(s)-clé(s) en anglais :

Fullerene
Cu(111)
self-assembly
ordering
STM
DFT
fullerene
epitaxy
energy landscape
surface alloy

Discipline(s) HAL :

Physique [physics]/Matière Condensée [cond-mat]/Science des matériaux [cond-mat.mtrl-sci]
Physique [physics]/Physique [physics]/Chimie-Physique [physics.chem-ph]

Résumé en anglais : [en]

The hybrid metal−organic interaction that molecular monolayers experience when deposited on metallic substrates can compete with intermolecular interactions and produce a variety of on-surface orders. The variety is already ...
Lire la suite >The hybrid metal−organic interaction that molecular monolayers experience when deposited on metallic substrates can compete with intermolecular interactions and produce a variety of on-surface orders. The variety is already important when the molecule/substrate interface remains atomically flat. Here, we address the case of fullerene molecules deposited at room temperature on a Cu(111) surface with interface atomic-scale roughening. Surprisingly, 10 distinct copper−fullerene phases are found to coexist. Their structure, i.e., the surface relative fullerene/Cu composition and commensurability relationship with the substrate, is resolved using scanning tunneling microscopy and density functional theory calculations. This diversity in the surface roughening process is associated with the multiple possibilities a fullerene can bind to the Cu surface. The molecules are indeed found to have in-plane and out-of-plane positional degrees of freedom: the molecular phases have elastic in-plane properties and can buckle. In addition, the molecules can rotate on their binding sites, conferring extra degrees of freedom to the system. We introduce a competing interaction energy model, parametrized against the results of ab initio calculations, that describes well all the phases we observe experimentally.Lire moins >

Langue :

Anglais

Comité de lecture :

Oui

Audience :

Internationale

Vulgarisation :

Non

Collections :

• Institut d'Électronique, de Microélectronique et de Nanotechnologie (IEMN) - UMR 8520

Source :

Harvested from HAL