Reactor development for a one-step hybrid catalytic conversion of D-glucose to HMF

Gimbernat, Alexandra; Heuson, Egon; Dumeignil, Franck; Delcroix, Damien; Girardon, Jean-Sébastien; Froidevaux, Rénato

Type de document :

Article dans une revue scientifique: Article original

DOI :

10.1002/cctc.202300713

URL permanente :

http://hdl.handle.net/20.500.12210/107926

Titre :

Reactor development for a one-step hybrid catalytic conversion of D-glucose to HMF

Auteur(s) :

Gimbernat, Alexandra [Auteur]
BioEcoAgro - UMR transfrontalière INRAe - UMRT1158
Heuson, Egon [Auteur]
Unité de Catalyse et Chimie du Solide (UCCS) - UMR 8181
Dumeignil, Franck [Auteur]

Unité de Catalyse et Chimie du Solide (UCCS) - UMR 8181
Delcroix, Damien [Auteur]
IFP Energies nouvelles [IFPEN]
Girardon, Jean-Sébastien [Auteur]

Unité de Catalyse et Chimie du Solide (UCCS) - UMR 8181
Froidevaux, Rénato [Auteur]

BioEcoAgro - UMR-T 1158

Titre de la revue :

ChemCatChem

Nom court de la revue :

ChemCatChem

Numéro :

Pagination :

e202300713

Date de publication :

2024-02-22

ISSN :

1867-3880

Mot(s)-clé(s) en anglais :

(bio)catalysis
Hybrid catalysis
2P-1S process
\"H\" reactor
5-hydroxymethylfurfural (HMF)

Discipline(s) HAL :

Chimie/Catalyse

Résumé en anglais : [en]

The design of an “H”-shaped reactor has been studied to satisfy the possibility of using a triphasic medium to transform d-glucose into 5-hydroxymethylfurfural (HMF) by a hybrid catalytic process using an immobilized glucose ...
Lire la suite >The design of an “H”-shaped reactor has been studied to satisfy the possibility of using a triphasic medium to transform d-glucose into 5-hydroxymethylfurfural (HMF) by a hybrid catalytic process using an immobilized glucose isomerase, allowing the isomerization of D-glucose to d-fructose, and a heterogeneous chemical catalyst to catalyze the dehydration of d-fructose to HMF. The various parameters influencing the transport of d-fructose within the reactor were studied, namely the difference in pH between the two aqueous phases, the agitation and the quantity of 3,4-DCPBA/Aliquat336® used to extract and transport continuously the d-fructose. The pH discrepancy, which must be between 5.0 and 5.5, turns out to be the real driving force behind the extraction of D-fructose. The D-Fru/3,4-DCPBA molar ratio of 1/0.25 allowed the transport of more than 80 % of the D-fructose initially present and shows that the same molecule of 3,4-DCPBA is involved at least twice in the transport of D-fructose and that the 3,4-DCPBA/Aliquat336® couple performs a turnover within the organic phase. Finally, a HMF production yield of 30.9 % and an isomerization yield of 79.1 % were obtained, illustrating the shift in the isomerization equilibrium made possible by a D-fructose extraction yield of 96.8 %.Lire moins >

Langue :

Anglais

Audience :

Internationale

Vulgarisation :

Non

Établissement(s) :

Université de Lille
CNRS
Centrale Lille
ENSCL
Univ. Artois

Collections :

Équipe(s) de recherche :

Valorisation des alcanes et de la biomasse (VAALBIO)

Date de dépôt :

2024-02-16T22:03:39Z
2024-02-27T13:55:46Z

Numéro de version	Lien	Date de modification
2	20.500.12210/107926*	2024-02-27T13:52:40Z
1	20.500.12210/107926.1	2024-02-16T22:03:39Z

Reactor development for a one-step hybrid ...

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Reactor development for a one-step hybrid ... BibTeX CSV Excel RIS

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Reactor development for a one-step hybrid ...

BibTeX

CSV

Excel

RIS