Title :

Crystal structure, spectroscopic characterization and Hirshfeld surface analysis of aquadichloridoN-[(pyridin-2-yl)methylidene]anilinecopper(II) monohydrate Molano Miguel F.

Author(s) :

Molano, Miguel F. [Auteur]
Universidad Pedagógica y Tecnológica de Colombia [UPTC]
Velasquez, Vaneza P. Lorett [Auteur]
Universidad Antonio Nariño [UAN]
Erben, Mauricio F. [Auteur]
Universidad Nacional de la Plata [Argentine] [UNLP]
Gonzalez, Diana L. Nossa [Auteur]
Universidad Nacional de la Plata [Argentine] [UNLP]
Loaiza, Alix E. [Auteur]
Pontificia Universidad Javeriana [PUJ]
Echeverri, Gustavo A. [Auteur]
Universidad Nacional de la Plata [Argentine] [UNLP]
Piro, Oscar E. [Auteur]
Universidad Nacional de la Plata [Argentine] [UNLP]
Tobon, Yeny A. [Auteur]
Laboratoire Avancé de Spectroscopie pour les Intéractions la Réactivité et l'Environnement - UMR 8516 [LASIRE]
Ben Tayeb Meziane, Karima [Auteur]
Laboratoire Avancé de Spectroscopie pour les Intéractions la Réactivité et l'Environnement (LASIRE) - UMR 8516
Castano, Jovanny A. Gomez [Auteur]
Universidad Pedagógica y Tecnológica de Colombia [UPTC]

Journal title :

Acta crystallographica Section E : Crystallographic communications [2015-...]

Volume number :

76

Pages :

148-154

Publication date :

2020

HAL domain(s) :

Planète et Univers [physics]/Sciences de la Terre

English abstract : [en]

The reaction of N-phenyl-1-(pyridin-2-yl)methanimine with copper chloride dihydrate produced the title neutral complex, [CuCl2(C12H10N2)(H2O)]·H2O. The CuII ion is five-coordinated in a distorted square-pyramidal geometry, ...
Show more >The reaction of N-phenyl-1-(pyridin-2-yl)methanimine with copper chloride dihydrate produced the title neutral complex, [CuCl2(C12H10N2)(H2O)]·H2O. The CuII ion is five-coordinated in a distorted square-pyramidal geometry, in which the two N atoms of the bidentate Schiff base, as well as one chloro and a water mol­ecule, form the irregular base of the pyramidal structure. Meanwhile, the apical chloride ligand inter­acts through a strong hydrogen bond with a water mol­ecule of crystallization. In the crystal, mol­ecules are arranged in pairs, forming a stacking of symmetrical cyclic dimers that inter­act in turn through strong hydrogen bonds between the chloride ligands and both the coordinated and the crystallization water mol­ecules. The mol­ecular and electronic structures of the complex were also studied in detail using EPR (continuous and pulsed), FT–IR and Raman spectroscopy, as well as magnetization measurements. Likewise, Hirshfeld surface analysis was used to investigate the inter­molecular inter­actions in the crystal packing.Show less >

Audience :

Non spécifiée

Popular science :

Non

Collections :

• Laboratoire Avancé de Spectroscopie pour les Intéractions la Réactivité et l'Environnement (LASIRE) - UMR 8516

Research team(s) :

Propriétés magnéto structurales des matériaux (PMSM)

Submission date :

2024-02-21T17:11:58Z
2024-02-23T09:12:31Z
2024-02-23T09:33:59Z
2024-02-23T11:35:24Z