In Situ Observation of Efflorescence and ...
Document type :
Article dans une revue scientifique: Article original
DOI :
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Title :
In Situ Observation of Efflorescence and Deliquescence Phase Transitions of Single NaCl and NaNO3 Mixture Particles in Air Using a Laser Trapping Technique
Author(s) :
Ishizaka, S. [Auteur]
Guo, F. Q. [Auteur]
Tian, X. M. [Auteur]
Seng, Samantha [Auteur]
Laboratoire Avancé de Spectroscopie pour les Intéractions la Réactivité et l'Environnement - UMR 8516 [LASIRE]
Tobon, Yeny [Auteur]
Laboratoire Avancé de Spectroscopie pour les Intéractions la Réactivité et l'Environnement (LASIRE) - UMR 8516
Sobanska, Sophie [Auteur]
Institut des Sciences Moléculaires [ISM]
Université de Bordeaux [UB]
Guo, F. Q. [Auteur]
Tian, X. M. [Auteur]
Seng, Samantha [Auteur]
Laboratoire Avancé de Spectroscopie pour les Intéractions la Réactivité et l'Environnement - UMR 8516 [LASIRE]
Tobon, Yeny [Auteur]
Laboratoire Avancé de Spectroscopie pour les Intéractions la Réactivité et l'Environnement (LASIRE) - UMR 8516
Sobanska, Sophie [Auteur]
Institut des Sciences Moléculaires [ISM]
Université de Bordeaux [UB]
Journal title :
Bulletin of the Chemical Society of Japan
Abbreviated title :
Bull. Chem. Soc. Jpn.
Volume number :
93
Pages :
86-91
Publication date :
2020-01-11
ISSN :
0009-2673
English keyword(s) :
Laser trapping
Aerosol
Raman spectroscopy
Aerosol
Raman spectroscopy
HAL domain(s) :
Chimie/Chimie théorique et/ou physique
English abstract : [en]
A novel experimental approach to study the hygroscopic properties of multi-component inorganic aerosols was demonstrated using a laser trapping technique. The efflorescence and deliquescence phase transitions of the equimolar ...
Show more >A novel experimental approach to study the hygroscopic properties of multi-component inorganic aerosols was demonstrated using a laser trapping technique. The efflorescence and deliquescence phase transitions of the equimolar mixture of NaCl and NaNO3 particles levitated in air were reversibly induced by controlling relative humidity. The two-stage phase transitions of the particles during the dehumidifying and humidifying processes were successfully observed in air. To our knowledge, this is the first experimental result to observe the reversible hygroscopic behavior of single optically-levitated multi-component inorganic aerosols in air. Furthermore, to elucidate the influence of solid substrates on the homogeneous and heterogeneous nucleation processes, the efflorescence relative humidity (ERH) and mutual efflorescence relative humidity (MERH) in air were compared with those observed on a hydrophobic glass substrate. The average ERH and MERH values of the NaCl–NaNO3 particles levitated in air were lower than those obtained for the particles deposited on the hydrophobic glass substrate.Show less >
Show more >A novel experimental approach to study the hygroscopic properties of multi-component inorganic aerosols was demonstrated using a laser trapping technique. The efflorescence and deliquescence phase transitions of the equimolar mixture of NaCl and NaNO3 particles levitated in air were reversibly induced by controlling relative humidity. The two-stage phase transitions of the particles during the dehumidifying and humidifying processes were successfully observed in air. To our knowledge, this is the first experimental result to observe the reversible hygroscopic behavior of single optically-levitated multi-component inorganic aerosols in air. Furthermore, to elucidate the influence of solid substrates on the homogeneous and heterogeneous nucleation processes, the efflorescence relative humidity (ERH) and mutual efflorescence relative humidity (MERH) in air were compared with those observed on a hydrophobic glass substrate. The average ERH and MERH values of the NaCl–NaNO3 particles levitated in air were lower than those obtained for the particles deposited on the hydrophobic glass substrate.Show less >
Language :
Anglais
Peer reviewed article :
Oui
Audience :
Internationale
Popular science :
Non
Administrative institution(s) :
Université de Lille
CNRS
CNRS
Collections :
Submission date :
2024-02-28T23:18:27Z
2024-03-12T13:41:39Z
2024-03-12T13:41:39Z
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