Synthesis of furfuryl alcohol from furfural: ...
Type de document :
Article dans une revue scientifique: Article original
DOI :
URL permanente :
Titre :
Synthesis of furfuryl alcohol from furfural: a comparison between batch and continuous flow reactors
Auteur(s) :
Audemar, Maite [Auteur]
Wang, Yantao [Auteur]
Zhao, Deyang [Auteur]
royer, sebastien [Auteur]
Unité de Catalyse et Chimie du Solide (UCCS) - UMR 8181
Jerome, Francois [Auteur]
Len, Christophe [Auteur]
Vigier, Karine De Oliveira [Auteur]
Wang, Yantao [Auteur]
Zhao, Deyang [Auteur]
royer, sebastien [Auteur]
Unité de Catalyse et Chimie du Solide (UCCS) - UMR 8181
Jerome, Francois [Auteur]
Len, Christophe [Auteur]
Vigier, Karine De Oliveira [Auteur]
Titre de la revue :
Energies
Numéro :
13
Date de publication :
2020-02-01
Mot(s)-clé(s) :
batch reactor
continuous flow
hydrogenation
furfuryl alcohol
furfural
continuous flow
hydrogenation
furfuryl alcohol
furfural
Discipline(s) HAL :
Chimie/Catalyse
Résumé en anglais : [en]
Furfural is a platform molecule obtained from hemicellulose. Among the products that can be produced from furfural, furfuryl alcohol is one of the most extensively studied. It is synthesized at an industrial scale in the ...
Lire la suite >Furfural is a platform molecule obtained from hemicellulose. Among the products that can be produced from furfural, furfuryl alcohol is one of the most extensively studied. It is synthesized at an industrial scale in the presence of CuCr catalyst, but this process suffers from an environmental negative impact. Here, we demonstrate that a non-noble metal catalyst (Co/SiO2) was active (100% conversion of furfural) and selective (100% selectivity to furfuryl alcohol) in the hydrogenation of furfural to furfuryl alcohol at 150 °C under 20 bar of hydrogen. This catalyst was recyclable up to 3 cycles, and then the activity decreased. Thus, a comparison between batch and continuous flow reactors shows that changing the reactor type helps to increase the stability of the catalyst and the space-time yield. This study shows that using a continuous flow reactor can be a solution to the catalyst suffering from a lack of stability in the batch process.Lire moins >
Lire la suite >Furfural is a platform molecule obtained from hemicellulose. Among the products that can be produced from furfural, furfuryl alcohol is one of the most extensively studied. It is synthesized at an industrial scale in the presence of CuCr catalyst, but this process suffers from an environmental negative impact. Here, we demonstrate that a non-noble metal catalyst (Co/SiO2) was active (100% conversion of furfural) and selective (100% selectivity to furfuryl alcohol) in the hydrogenation of furfural to furfuryl alcohol at 150 °C under 20 bar of hydrogen. This catalyst was recyclable up to 3 cycles, and then the activity decreased. Thus, a comparison between batch and continuous flow reactors shows that changing the reactor type helps to increase the stability of the catalyst and the space-time yield. This study shows that using a continuous flow reactor can be a solution to the catalyst suffering from a lack of stability in the batch process.Lire moins >
Langue :
Anglais
Audience :
Internationale
Vulgarisation :
Non
Établissement(s) :
CNRS
Centrale Lille
ENSCL
Univ. Artois
Université de Lille
Centrale Lille
ENSCL
Univ. Artois
Université de Lille
Collections :
Équipe(s) de recherche :
Matériaux pour la catalyse (MATCAT)
Date de dépôt :
2022-03-02T07:14:30Z
2024-01-15T16:24:03Z
2024-01-15T16:24:03Z
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