Tuning the Lewis acidity of metal-organic ...
Document type :
Article dans une revue scientifique: Article original
DOI :
PMID :
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Title :
Tuning the Lewis acidity of metal-organic frameworks for enhanced catalysis
Author(s) :
Devulapalli, Venkata Swaroopa Datta [Auteur]
Temple University [Philadelphia]
Richard, Mélissandre [Auteur]
Temple University [Philadelphia]
Luo, Tian-Yi [Auteur]
University of Pittsburgh [PITT]
De Souza, Mattheus L. [Auteur]
University of Pittsburgh [PITT]
Rosi, Nathaniel L. [Auteur]
University of Pittsburgh [PITT]
Borguet, Eric [Auteur]
Temple University [Philadelphia]
Temple University [Philadelphia]
Richard, Mélissandre [Auteur]

Temple University [Philadelphia]
Luo, Tian-Yi [Auteur]
University of Pittsburgh [PITT]
De Souza, Mattheus L. [Auteur]
University of Pittsburgh [PITT]
Rosi, Nathaniel L. [Auteur]
University of Pittsburgh [PITT]
Borguet, Eric [Auteur]
Temple University [Philadelphia]
Journal title :
Dalton Transactions
Abbreviated title :
Dalton Trans
Volume number :
50
Pages :
3116-3120
Publisher :
Royal Society of Chemistry (RSC)
Publication date :
2021-02-10
ISSN :
1477-9234
HAL domain(s) :
Chimie/Catalyse
English abstract : [en]
The kinetics of hydrolysis of dimethyl nitrophenyl phosphate (DMNP), a simulant of the nerve agent Soman, was studied and revealed transition metal salts as catalysts. The relative rates of DMNP hydrolysis by zirconium and ...
Show more >The kinetics of hydrolysis of dimethyl nitrophenyl phosphate (DMNP), a simulant of the nerve agent Soman, was studied and revealed transition metal salts as catalysts. The relative rates of DMNP hydrolysis by zirconium and hafnium chlorides are in accordance with their Lewis acidity. In situ conversion of zirconium chloride to zirconium oxy-hydroxide was identified as the key step. We propose a precursor-MOF activity relationship.Show less >
Show more >The kinetics of hydrolysis of dimethyl nitrophenyl phosphate (DMNP), a simulant of the nerve agent Soman, was studied and revealed transition metal salts as catalysts. The relative rates of DMNP hydrolysis by zirconium and hafnium chlorides are in accordance with their Lewis acidity. In situ conversion of zirconium chloride to zirconium oxy-hydroxide was identified as the key step. We propose a precursor-MOF activity relationship.Show less >
Language :
Anglais
Audience :
Internationale
Popular science :
Non
Administrative institution(s) :
Université de Lille
CNRS
Centrale Lille
ENSCL
Univ. Artois
CNRS
Centrale Lille
ENSCL
Univ. Artois
Collections :
Submission date :
2023-05-30T15:35:08Z
2023-06-21T11:23:08Z
2023-11-10T10:40:51Z
2023-11-17T11:01:27Z
2023-11-17T11:58:50Z
2023-12-08T14:47:50Z
2023-12-15T14:59:31Z
2023-06-21T11:23:08Z
2023-11-10T10:40:51Z
2023-11-17T11:01:27Z
2023-11-17T11:58:50Z
2023-12-08T14:47:50Z
2023-12-15T14:59:31Z
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