Tuning the Lewis acidity of metal-organic ...
Type de document :
Article dans une revue scientifique: Article original
DOI :
PMID :
URL permanente :
Titre :
Tuning the Lewis acidity of metal-organic frameworks for enhanced catalysis
Auteur(s) :
Devulapalli, Venkata Swaroopa Datta [Auteur]
Temple University [Philadelphia]
Richard, Mélissandre [Auteur]
Temple University [Philadelphia]
Luo, Tian-Yi [Auteur]
University of Pittsburgh [PITT]
De Souza, Mattheus L. [Auteur]
University of Pittsburgh [PITT]
Rosi, Nathaniel L. [Auteur]
University of Pittsburgh [PITT]
Borguet, Eric [Auteur]
Temple University [Philadelphia]
Temple University [Philadelphia]
Richard, Mélissandre [Auteur]
![refId](/themes/Mirage2//images/idref.png)
Temple University [Philadelphia]
Luo, Tian-Yi [Auteur]
University of Pittsburgh [PITT]
De Souza, Mattheus L. [Auteur]
University of Pittsburgh [PITT]
Rosi, Nathaniel L. [Auteur]
University of Pittsburgh [PITT]
Borguet, Eric [Auteur]
Temple University [Philadelphia]
Titre de la revue :
Dalton Transactions
Nom court de la revue :
Dalton Trans
Numéro :
50
Pagination :
3116-3120
Éditeur :
Royal Society of Chemistry (RSC)
Date de publication :
2021-02-10
ISSN :
1477-9234
Discipline(s) HAL :
Chimie/Catalyse
Résumé en anglais : [en]
The kinetics of hydrolysis of dimethyl nitrophenyl phosphate (DMNP), a simulant of the nerve agent Soman, was studied and revealed transition metal salts as catalysts. The relative rates of DMNP hydrolysis by zirconium and ...
Lire la suite >The kinetics of hydrolysis of dimethyl nitrophenyl phosphate (DMNP), a simulant of the nerve agent Soman, was studied and revealed transition metal salts as catalysts. The relative rates of DMNP hydrolysis by zirconium and hafnium chlorides are in accordance with their Lewis acidity. In situ conversion of zirconium chloride to zirconium oxy-hydroxide was identified as the key step. We propose a precursor-MOF activity relationship.Lire moins >
Lire la suite >The kinetics of hydrolysis of dimethyl nitrophenyl phosphate (DMNP), a simulant of the nerve agent Soman, was studied and revealed transition metal salts as catalysts. The relative rates of DMNP hydrolysis by zirconium and hafnium chlorides are in accordance with their Lewis acidity. In situ conversion of zirconium chloride to zirconium oxy-hydroxide was identified as the key step. We propose a precursor-MOF activity relationship.Lire moins >
Langue :
Anglais
Audience :
Internationale
Vulgarisation :
Non
Établissement(s) :
Université de Lille
CNRS
Centrale Lille
ENSCL
Univ. Artois
CNRS
Centrale Lille
ENSCL
Univ. Artois
Collections :
Date de dépôt :
2023-05-30T15:35:08Z
2023-06-21T11:23:08Z
2023-11-10T10:40:51Z
2023-11-17T11:01:27Z
2023-11-17T11:58:50Z
2023-06-21T11:23:08Z
2023-11-10T10:40:51Z
2023-11-17T11:01:27Z
2023-11-17T11:58:50Z
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- Dalton Transactions_D1DT00180A_DMNP_catalysis_proof.pdf
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