Pillar[5]arenes-based high-Tg thermosets for the capture of volatile organic compounds

Ritaine, Solenne; Ternel, Valentin; Woisel, Patrice; Claverie, Jerome P.; Potier, Jonathan

Type de document :

Article dans une revue scientifique: Article original

DOI :

10.1039/d3nj02422a

URL permanente :

http://hdl.handle.net/20.500.12210/93658

Titre :

Pillar[5]arenes-based high-Tg thermosets for the capture of volatile organic compounds

Auteur(s) :

Ritaine, Solenne [Auteur]
Unité Matériaux et Transformations - UMR 8207 [UMET]
Ternel, Valentin [Auteur]
Unité Matériaux et Transformations (UMET) - UMR 8207
Woisel, Patrice [Auteur]

Unité Matériaux et Transformations (UMET) - UMR 8207
Claverie, Jerome P. [Auteur]
Faculté des sciences [Sherbrooke] [UdeS]
Potier, Jonathan [Auteur]

Unité Matériaux et Transformations (UMET) - UMR 8207

Titre de la revue :

New Journal of Chemistry

Nom court de la revue :

New J. Chem.

Numéro :

Pagination :

15021-15026

Éditeur :

Royal Society of Chemistry (RSC)

Date de publication :

2023

Discipline(s) HAL :

Chimie/Matériaux

Résumé en anglais : [en]

Volatile organic compounds (VOCs) continue to be one of the biggest problems for air quality and it is becoming increasingly urgent to find new systems capable of limiting their concentration in the atmosphere. Thanks to ...
Lire la suite >Volatile organic compounds (VOCs) continue to be one of the biggest problems for air quality and it is becoming increasingly urgent to find new systems capable of limiting their concentration in the atmosphere. Thanks to their capacity to recognize halogenated derivatives, Pillar[5]arenes were used to form high performance thermosets able to absorb chlorine and bromide-based VOCs. Initially, poly(2-vinyl-4,4-dimethylazlactone) featuring different chain length were synthetized and modified by ring opening reaction by mono-amino substituted P[5]A. The high-Tg polymers obtained were then crooslinked by isophore diamine to form high performance materials featuring Tg up to 150 °C and storac modulus G′ up to 85 MPa. The ability of P[5]A cavities to capt VOCs was investigated by vapor sorption tests in presence of dichloromethane, 1,2-dibromoethane, dibromochloromethane and 1,1,2,2-tetrachloroethane. The P[5]A-based thermosets shown to be efficient to absord these carcenogenic VOCs and, this efficiency depends on the affinity of cavities for the studied VOCs, proving that these new generation of thermosets seems to be selective towards certain VOCs.Lire moins >

Langue :

Anglais

Comité de lecture :

Oui

Audience :

Internationale

Vulgarisation :

Non

Établissement(s) :

Université de Lille
CNRS
INRAE
ENSCL

Collections :

Unité Matériaux et Transformations (UMET) - UMR 8207

Équipe(s) de recherche :

Ingénierie des Systèmes Polymères

Date de dépôt :

2023-12-19T06:47:37Z
2023-12-20T10:49:21Z

Numéro de version	Lien	Date de modification
2	20.500.12210/93658*	2023-12-20T10:43:20Z
1	20.500.12210/93658.1	2023-12-19T06:47:37Z

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Pillar[5]arenes-based high-Tg thermosets ...

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